I've just got a real quick concept I wanted to share. I've just started a 10 week masterclass on educational science which has me studying 12 hrs per week so I did not have time to build out the full thing.
In this concept I used Articulate Replay to record myself and used Storyline to add interactive element on top of the video layer.
Now in the demo the links to my experience, education and work aren't doing anything but I imagine more short clips and interactive elements. For example the portfolio page could have some polaroids flying in which can open a lightbox window with a more detailed view. The Experience screen could have various company logos pop up and dragging them into a drop-area would reveal the details of that job.
Lot's of possibilities!
http://www.seriouslearning.nl/challenges/resume/story.html